It is used in the preparation of P,N ligands for asymmetric Ir-catalyzed reactions.
Seung-Hoi Kim.;Reuben D. Rieke. 2-Pyridyl and 3-pyridylzinc bromides: direct preparation and coupling reaction. Tetrahedron. 2010, 66(17),3135-3146.
Seung-Hoi Kim.; Reuben D. Rieke. A facile synthetic route for 2-pyridyl derivatives: direct preparation of a stable 2-pyridylzinc bromide and its copper-free and pd-catalyzed coupling reactions. Tetrahedron Lett. 2009, 50(38),5329-5331.
危险说明(欧盟):H225-H302-H314-H335-H336-H351b
Highly flammable liquid and vapour. Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer if inhaled
防范说明:P201-P202-P242-P260-P264b-P270-P271-P281-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378r-P403+P233-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/ container to an approved waste disposal plant




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