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主营:分子类,蛋白类,抗体类,生化类试剂
℡ 4000-520-616
℡ 4000-520-616
alfa/44506µ-Chloro-µ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene/25ml/44506.AC
产品编号:44506.AC
市  场 价:¥80380.00
场      地:美国(厂家直采)
产品分类: 蛋白类>多肽>多肽合成>
联系QQ:1570468124
电话号码:4000-520-616
邮      箱: info@ebiomall.com
美  元  价:$4019.00
品      牌: alfa
公      司:alfa
公司分类:
alfa/44506µ-Chloro-µ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene/25ml/44506.AC
商品介绍

µ-Chloro-µ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene

MDL
MFCD00151575

化学性质

化学式
C13H18AlClTi
式量
284.62
表格
Liquid
闪点
1°(34°F)
密度
0.927
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Nitrogen.Ambient temperatures.
可溶性
Soluble in toluene, benzene, dichloromethane. Insoluble in water.

应用

µ-Chloro-µ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.

注释

Air & Moisture Sensitive

参考文献

GHS危险和防护声明

危险说明(欧盟):H225-H304-H314-H336-H361-H373-H412

Highly flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. Harmful to aquatic life with long lasting effects.

防范说明:P201-P202-P242-P260-P264b-P271-P281-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378r-P403+P233-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only non-sparking tools. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. In case of fire: Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/ container to an approved waste disposal plant

其他参考资料

默克登记号
14,9091
危险等级
3
包装组别
II
协调关税代码
2931.90
有毒物质控制法
No

文件

产品 SDS

质量分析报告(COA)

品牌介绍

Alfa Aesar (阿法埃莎) 是全球首屈一指的科研化学品、金属和材料的生产商及供应商。半个世纪以来,无数科研人员凭借Alfa Aesar提供的高纯度原材料进行了各类研究和开发工作。如今,我们的产品种类已超过46000种,可以提供从克级到吨级的规格。除此之外,我们还可以根据客户需求定制特殊产品。这些均使得我们成为科研化学品、金属及材料的一站式供应商。

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