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主营:分子类,蛋白类,抗体类,生化类试剂
℡ 4000-520-616
℡ 4000-520-616
alfa/10491trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min/1g/10491.03
产品编号:10491.03
市  场 价:¥10200.00
场      地:美国(厂家直采)
产品分类: 蛋白类>多肽>多肽合成>
联系QQ:1570468124
电话号码:4000-520-616
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美  元  价:$510.00
品      牌: alfa
公      司:alfa
公司分类:
alfa/10491trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min/1g/10491.03
商品介绍

trans-Dichlorobis(triphenylphosphine)palladium(II), Pd 14.0% min

MDL
MFCD00009593
EINECS
237-744-2

化学性质

化学式
C36H30Cl2P2Pd
式量
701.91
表格
Crystalline
熔点
ca 310° dec.
Storage & Sensitivity
Hygroscopic.Ambient temperatures.
可溶性
Insoluble in water.Soluble in benzene, and toluene.

应用

As a catalyst of choice in hydrogenation, hydrosilation, carbonylation, oxidation, elimination, reduction, allyl aceate isomerization, dimerization of 1,3-dienes,and C-C bond formation such as Negishi coupling, Suzuki coupling, Kumada coupling, Sonogashira coupling, Heck coupling and Sonogashira-Hagihara coupling reactions.Used in the preparation of tetrakis(triphenylphosphine)palladium, condensed heterocycles such as furoquinolines, diphenylacetylenes, and several other compounds.

注释

Stable at room temperature. Air, light and moisture sensitive.Incompatible with strong oxidising agents.

参考文献

Talhami, A.; Penn, L.; Jaber, N.; Hamza, K.; Blum, J. Sol-gel Entrapped Dichlorobis(triphenylphosphine)palladium as an Efficient Recyclable Catalyst for the Cross-coupling of Aryl Halides with Indium- and related Alkylating Reagents. Appl. Catal., A 2006, 312,115-119.

Evans, P. J.; Darzi, E. R.; Jasti, R. Efficient room-temperature synthesis of a highly strained carbon nanohoop fragment of buckminsterfullerene. Nat. Chem. 2014, 6,404-408.

Abe, Y.; Aoki, T.; Jia, H.; Hadano, S.; Namikoshi, T.; Kakihana, Y.; Liu, L.; Zang, Y.; Teraguchi, M.; Kaneko, T.Synthesis of Stable and Soluble One-Handed Helical Homopoly(substituted acetylene)s without the Coexistence of Any Other Chiral Moieties via Two-Step Polymer Reactions in Membrane State: Molecular Design of the Starting Monomer. Molecules 2012, 17,433-451.

GHS危险和防护声明

防范说明:P403-P501c

Store in a well-ventilated place. Dispose of contents/ container to an approved waste disposal plant

其他参考资料

协调关税代码
2843.90
有毒物质控制法
No
化学物质毒性数据库登记号
RT3578000

文件

产品 SDS

质量分析报告(COA)

产品说明书

品牌介绍

Alfa Aesar (阿法埃莎) 是全球首屈一指的科研化学品、金属和材料的生产商及供应商。半个世纪以来,无数科研人员凭借Alfa Aesar提供的高纯度原材料进行了各类研究和开发工作。如今,我们的产品种类已超过46000种,可以提供从克级到吨级的规格。除此之外,我们还可以根据客户需求定制特殊产品。这些均使得我们成为科研化学品、金属及材料的一站式供应商。

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