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主营:分子类,蛋白类,抗体类,生化类试剂
℡ 4000-520-616
℡ 4000-520-616
alfa/11034Palladium(II) chloride, 99.9% (metals basis), Pd 59.0% min/50g/11034.18
产品编号:11034.18
市  场 价:¥485480.00
场      地:美国(厂家直采)
产品分类: 蛋白类>多肽>多肽合成>
联系QQ:1570468124
电话号码:4000-520-616
邮      箱: info@ebiomall.com
美  元  价:$24274.00
品      牌: alfa
公      司:alfa
公司分类:
alfa/11034Palladium(II) chloride, 99.9% (metals basis), Pd 59.0% min/50g/11034.18
商品介绍

Palladium(II) chloride, 99.9% (metals basis), Pd 59.0% min

MDL
MFCD00003558
EINECS
231-596-2

化学性质

化学式
PdCl2
式量
177.31
表格
Crystalline
熔点
675° dec.
密度
4.0
Storage & Sensitivity
Ambient temperatures.
可溶性
Soluble in dilute mineral acids, aqueous metal halides.Soluble in cold water, organic solvents and hydrochloric acid.

应用

Catalyst precursor.Palladium(II) chloride is used to remove the stain present in stainless steel . Its solutions are used to test the corrosion-resistance of stainless steel. It is used in carbon monoxide detectors. It is also used for cosmetic tattooing of leukomas in the cornea and in the preparation of palladium(II) iodide by reacting with potassium iodide. It is involved in the synthesis of semiconducting metal-containing polymers. It is used as a catalyst for carbonylation of organic tellurides and deamination of phenethylamines to phenyl substituted pyrroles with copper(I) as co catalyst. It plays an important role in the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.

注释

Incompatible with organic solvents, acids, ammonia, zinc, strong oxidizing agents, aluminum, magnesium, nitratesand thiocyanates.

参考文献

Yamaguchi, T.; Yamaguchi, E.; Tada, N.; Itoh, A. Direct ortho-Hydroxylation of 2-Phenylpyridines using Palladium(II) Chloride and Hydrogen Peroxide. Adv. Synth. Catal. 2015, 357 (9), 2017-2021.

Banti, C. N.; Charalampou, D. C.; Kourkoumelis, N.; Owczarzak, A. M.; Kubicki, M.; Hadjikakou, S. K.; Hadjiliadis, N. Mono-nuclear cis-Pd(II) chloride complex of the thio-nucleotide analogue 5-methyl-thiouracil and its biological activity. Polyhedron 2015, 87, 251-258.

Janreddy, D.; Kavala, V.; Kotipalli, T.; Kuo, C.; Kuo, T.; Chen, M.; He, T.; Yao, C. Palladium(II) Chloride-Catalyzed Aerobic Oxidative Intermolecular Cycloaddition Reaction of 2-Alkynylbenz- aldehydes and Electron-Deficient Terminal Alkenes: An Efficient Synthesis of Naphthyl Ketones. Adv. Synth. Catal. 2014, 356 (14-15), 3083-3091.

GHS危险和防护声明

危险说明(欧盟):H290-H302-H317-H318-H410

May be corrosive to metals. Harmful if swallowed. May cause an allergic skin reaction. Causes serious eye damage. Very toxic to aquatic life with long lasting effects.

防范说明:P261-P264b-P270-P272-P280-P302+P352-P305+P351+P338-P310-P330-P363-P390-P406b-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Store in corrosive resistant polypropylene container with a resistant inliner Dispose of contents/ container to an approved waste disposal plant

其他参考资料

默克登记号
14,6990
危险等级
8
包装组别
III
协调关税代码
2843.90
有毒物质控制法
Yes
化学物质毒性数据库登记号
RT3500000

文件

产品 SDS

质量分析报告(COA)

产品说明书

品牌介绍

Alfa Aesar (阿法埃莎) 是全球首屈一指的科研化学品、金属和材料的生产商及供应商。半个世纪以来,无数科研人员凭借Alfa Aesar提供的高纯度原材料进行了各类研究和开发工作。如今,我们的产品种类已超过46000种,可以提供从克级到吨级的规格。除此之外,我们还可以根据客户需求定制特殊产品。这些均使得我们成为科研化学品、金属及材料的一站式供应商。

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