![alfa/44829Dichloro[1,1-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3%/0.25g/44829.01](images/alfa/44829.gif)
Dichloro[1,1"-bis(di-tert-butylphosphino)ferrocene]palladium(II), Pd 16.3%
化学性质
应用
Coupling reactions, Suzuki couplings.Dichloro[1,1"-bis(di-tert-butylphosphino)ferrocene] palladium(II) is used as a catalyst in Suzuki-cross coupling reactions, which involve reaction of aromatic halides with methyliminodiacetic acid derivatives. it is also used as a catalyst for the preparation of chalcones. It is used in the preparation of (bisphosphinometallocene)-palladium(II) chloride complexes, which used as a starting material for the Buchwald-Hartwig reaction.
注释
参考文献
Colacot, T. J. The 2010 Nobel Prize in chemistry: palladium-catalysed cross-coupling. Platinum Met. Rev. 2011, 55 (2), 84-90.
Lipshutz, B. H.; Taft, B. R.; Abela, A. R.; Ghorai, S.; Krasovskiy, A.; Duplais, C. Catalysis in the service of green chemistry: Nobel prize-winning palladium-catalysed cross-couplings, run in water at room temperature: Heck, Suzuki-miyaura and Negishi reactions carried out in the absence of organic solvents, enabled by micellar catalysis. Platinum Met. Rev. 2012, 56 (2), 62-74.
GHS危险和防护声明
危险说明（欧盟）:H302+H312+H332-H315-H319
Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation.
防范说明:P261-P264b-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P330-P362-P403-P501c
Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Dispose of contents/ container to an approved waste disposal plant
其他参考资料
文件
产品 SDS
质量分析报告(COA)
产品说明书
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